BrainMap

Mr. Mihail Iacob

Ph.D.

Researcher - INSTITUTUL DE CHIMIE MACROMOLECULARA "PETRU PONI"

Other affiliations

Lecturer - Tiraspol State University (Moldova, Republic of)

Researcher

Web of Science ResearcherID: not public

Curriculum Vitae (09/01/2019)

Expertise & keywords

New coordination networks containing polyfunctional flexible bridges Call name: Exploratory Research Projects - PCE-2012 call
PN-II-ID-PCE-2012-4-0261 2013 - 2016

Role in this project: Key expert

Coordinating institution: INSTITUTUL DE CHIMIE MACROMOLECULARA "PETRU PONI"

Project partners: INSTITUTUL DE CHIMIE MACROMOLECULARA "PETRU PONI" (RO)

Affiliation: INSTITUTUL DE CHIMIE MACROMOLECULARA "PETRU PONI" (RO)

Project website: http://www.icmpp.ro/cazacu0261/pce_2012_4_0261_en_2016.ppt; http://www.icmpp.ro/cazacu0261/pce_2012_4_0261_ro_2016.ppt

Abstract:

The project aim is to bring developments in the metal-containing materials field by the preparation of new metal-organic networks using ligands with high flexible siloxane spacer between the complexing groups. Networks having single metal ions or polynuclear clusters as nodes will be prepared. The later will be obtained and subsequently used as secondary building units (SBUs) or generated in situ concomitantly with the network formation. Original di- tetra- and polycarboxylic acids as well as amine ligands containing siloxane moieties will be used as SBUs for the metal-organic structures infinitely extended into one, two or three dimensions (1D, 2D or 3D, respectively) via more or less covalent metal-ligand bonding. The siloxane moieties confer flexibility to the networks, thus structural adjustment through rotations and twists of structural units are expected, leading to better uptake of different guest molecules. Both building blocks (siloxane ligands and metal clusters) and networks prepared on their basis will be fully characterized from structural point of view by using adequate techniques (elemental, spectroscopic, X-ray diffraction). The specific properties (as for example: sorbtion behavior, magnetic, catalytic, biological, etc.) will be evaluated in order to identify possible applications of the new materials.

FILE DESCRIPTION	DOCUMENT
List of research grants as project coordinator or partner team leader
Significant R&D projects for enterprises, as project manager
R&D activities in enterprises
Peer-review activity for international programs/projects