BrainMap

Iulia-Andreea Aghion

- UNIVERSITATEA BABES BOLYAI

PhD student

Expertise & keywords

Towards novel class of coordinative compounds based on diphospapropene and diphosphaallene ligands. Call name: P 1 - SP 1.1 - Proiecte de cercetare pentru stimularea tinerelor echipe independente
PN-III-P1-1.1-TE-2019-2085 2020 - 2022

Role in this project:

Coordinating institution: UNIVERSITATEA BABES BOLYAI

Project partners: UNIVERSITATEA BABES BOLYAI (RO)

Affiliation:

Project website: http://www.chem.ubbcluj.ro/pagini/anorganica/clcpe/research_grants2_en.html

Abstract:

The chemistry of unsaturated phosphorus derivatives containing the P=C-P(=E) and P=C=P(=E) (E=chalcogen) backbones, namely 1,3-diphosphapropenes and 1,3-diphosphaallenes has a great number of aspects left to explore. Due to the multiple coordination sites (the lone pair of the trivalent phosphorus atom, the lone pair of the chalcogen atom and the unsaturated bonds) these class of ligands can lead to an impressive number of metal complexes. The main goal of the project proposal focuses on the design, preparation and characterization of new compounds containing the P=C-P=E or P=C=P=E (E=chalcogen) units stabilized with various organic groups on the phosphorus atoms and their use as ligands to two different d-block metal fragments or a transition metal and a p-metal or semimetal. Depending on the nature of the metal, the selective coordination through the phosphorus or the chalcogen atoms can be achieved and thus can lead to the preparation of coordinative species having interesting electronic, magnetic, or applicative properties. Achieving the proposed goal of the project will impact not only on the fundamental research, but it also could afford compounds that can be used for the obtaining of highly selective derivatives with potential biological activity.

FILE DESCRIPTION	DOCUMENT
List of research grants as project coordinator or partner team leader
Significant R&D projects for enterprises, as project manager
R&D activities in enterprises
Peer-review activity for international programs/projects